{ "ok": true, "doi": "10.46243/jst.2023.v8.i10.pp40-57", "events": [ { "seq": 1, "kind": "register", "at": "2026-09-29 22:00:32", "by": "Administrator (admin)", "by_kind": "user", "note": "registered at Crossref; record read from api.crossref.org", "changes": [ { "path": "abstract.lang", "from": null, "to": "en" }, { "path": "abstract.value", "from": null, "to": "LGHCl - Semi-organic single crystals of L-Glutamic acid hydrochloride, optical material have been grown by the solvent evaporation route. Powder X-ray diffraction and FT-IR analysis confirmed the formation of LGHCl crystals. The optical second harmonic generation (SHG) conversion efficiency of LGHCl was determined by the Kurtz-Perry powder technique, and it is found to be 1.62 times that of potassium dihydrogen phosphate. Through the SHG dependency of average particle sizes, the relative SHG efficiency of the crystal and the phase matching characteristic of the crystal were explored. The dielectric behaviour of LGHCl single crystal as a function of temperature was examined (300–350 K). The crystal’s photoconductive properties were investigated in order to determine its photocurrent and dark current responses. The Vickers microharness analysis at room temperature was used to evaluate the mechanical hardness of the generated LGHCl single crystal. Natural bond orbital (NBO) analysis was used to investigate the molecule’s stability as a result of hyperconjugation and charge delocalization interaction. Furthermore, the total and partial density of states in the title compound was also determined. The obtained results indicate that the molecule is thermodynamically and optically stable, with a hyperpolarizability that is comparable to other molecules in its class." }, { "path": "agents.0.name.family", "from": null, "to": "Mr S S Saravanakumar" }, { "path": "agents.0.name.given", "from": null, "to": "" }, { "path": "agents.0.role", "from": null, "to": "author" }, { "path": "agents.0.sequence", "from": null, "to": "first" }, { "path": "agents.1.name.family", "from": null, "to": "Dr. M S Sameema" }, { "path": "agents.1.name.given", "from": null, "to": "" }, { "path": "agents.1.role", "from": null, "to": "author" }, { "path": "agents.1.sequence", "from": null, "to": "additional" }, { "path": "agents.2.name.family", "from": null, "to": "Dr. P. Sivakumar" }, { "path": "agents.2.name.given", "from": null, "to": "" }, { "path": "agents.2.role", "from": null, "to": "author" }, { "path": "agents.2.sequence", "from": null, "to": "additional" }, { "path": "agents.3.name.family", "from": null, "to": "Dr. N. Sasirekha" }, { "path": "agents.3.name.given", "from": null, "to": "" }, { "path": "agents.3.role", "from": null, "to": "author" }, { "path": "agents.3.sequence", "from": null, "to": "additional" }, { "path": "agents.4.name.org", "from": null, "to": "Longman Publishers" }, { "path": "agents.4.role", "from": null, "to": "publisher" }, { "path": "characters.0", "from": null, "to": "Language" }, { "path": "container.identifiers.0.medium", "from": null, "to": "electronic" }, { "path": "container.identifiers.0.type", "from": null, "to": "ISSN" }, { "path": "container.identifiers.0.value", "from": null, "to": "2456-5660" }, { "path": "container.issue", "from": null, "to": "10" }, { "path": "container.pages.first", "from": null, "to": "40" }, { "path": "container.pages.last", "from": null, "to": "57" }, { "path": "container.titles.0.type", "from": null, "to": "PrincipalTitle" }, { "path": "container.titles.0.value", "from": null, "to": "Journal of Science & Technology" }, { "path": "container.type", "from": null, "to": "Journal" }, { "path": "container.volume", "from": null, "to": "08" }, { "path": "dates.date_type", "from": null, "to": "PublicationDate" }, { "path": "dates.online", "from": null, "to": "2023" }, { "path": "dates.published", "from": null, "to": "2023" }, { "path": "doi", "from": null, "to": "10.46243/jst.2023.v8.i10.pp40-57" }, { "path": "format", "from": null, "to": "smartscholars-doi-metadata/1.0" }, { "path": "identifiers.0.type", "from": null, "to": "DOI" }, { "path": "identifiers.0.value", "from": null, "to": "10.46243/jst.2023.v8.i10.pp40-57" }, { "path": "language", "from": null, "to": "en" }, { "path": "license.applies_to", "from": null, "to": "vor" }, { "path": "license.start", "from": null, "to": "2023-01-01" }, { "path": "license.url", "from": null, "to": "https://creativecommons.org/licenses/by/4.0/" }, { "path": "links.0.primary", "from": null, "to": true }, { "path": "links.0.return_type", "from": null, "to": "text/html" }, { "path": "links.0.url", "from": null, "to": "https://www.jst.org.in/index.php/pub/article/view/807" }, { "path": "links.1.purpose", "from": null, "to": "text-mining" }, { "path": "links.1.return_type", "from": null, "to": "application/pdf" }, { "path": "links.1.url", "from": null, "to": "https://www.jst.org.in/index.php/pub/article/download/807/739" }, { "path": "links.2.purpose", "from": null, "to": "text-mining" }, { "path": "links.2.return_type", "from": null, "to": "application/xml" }, { "path": "links.2.url", "from": null, "to": "https://www.jst.org.in/index.php/pub/article/download/807/1631" }, { "path": "links.3.purpose", "from": null, "to": "similarity-checking" }, { "path": "links.3.url", "from": null, "to": "https://jst.org.in/index.php/pub/article/view/807/739" }, { "path": "modes.0", "from": null, "to": "Visual" }, { "path": "record.issue_number", "from": null, "to": 1 }, { "path": "record.registered", "from": null, "to": "2026-08-27" }, { "path": "record.registrant", "from": null, "to": "Longman Publishers" }, { "path": "record.source", "from": null, "to": "crossref-api" }, { "path": "record.source_agency", "from": null, "to": "Crossref (member 25296)" }, { "path": "record.updated", "from": null, "to": "2026-09-26" }, { "path": "references.0.key", "from": null, "to": "ref1" }, { "path": "references.0.unstructured", "from": null, "to": "Acharya, K. P.: Photo current Spectroscopy of CdS/ Plastic, CdS/Glass, and ZnTe /Ga As Hetero-pairs Formed with Pulsed Laser Deposition. Ph.D. Thesis, Bowling Green State University, 2009" }, { "path": "references.1.doi", "from": null, "to": "10.1007/s12043-008-0152-7" }, { "path": "references.1.key", "from": null, "to": "ref2" }, { "path": "references.1.unstructured", "from": null, "to": "Bhattacharya, R.; Saha,S.: Growth of CdS Nanoparticles by Chemical Method and its Characterization. Pramana-Journal of Physics 2008, 71, 187-192" }, { "path": "references.10.doi", "from": null, "to": "10.1021/ja970754m" }, { "path": "references.10.key", "from": null, "to": "ref11" }, { "path": "references.10.unstructured", "from": null, "to": "X.G. Peng, M.C. Schlamp, A.V. Kadavanich and A.P. Alivisatos, J. Am. Chem. Soc., 119 (1997) 7019–7029" }, { "path": "references.11.doi", "from": null, "to": "10.1016/j.matchemphys.2004.11.015" }, { "path": "references.11.key", "from": null, "to": "ref12" }, { "path": "references.11.unstructured", "from": null, "to": "X. Liu, Mater. Chem. Phys., 91 (2005) 212–216" }, { "path": "references.12.key", "from": null, "to": "ref13" }, { "path": "references.12.unstructured", "from": null, "to": "D. Ghanbari, M. Salavati-Niasari, S. Karimzadeh and S. Gholamrezaei, J. NanoStruct., 4 (2014) 227–232" }, { "path": "references.13.key", "from": null, "to": "ref14" }, { "path": "references.13.unstructured", "from": null, "to": "G. Nabiyouni, S. Sharifi, D. Ghanbari and M. Salavati-Niasari, J. NanoStruct., 4 (2014) 317–323" }, { "path": "references.14.key", "from": null, "to": "ref15" }, { "path": "references.14.unstructured", "from": null, "to": "M. Panahi-Kalamuei, M. Mousavi-Kamazani and M. Salavati-Niasari, J. NanoStruct., 4 (2014) 459–465" }, { "path": "references.15.key", "from": null, "to": "ref16" }, { "path": "references.15.unstructured", "from": null, "to": "F. Beshkar and M. Salavati-Niasari, J. NanoStruct., 5 (2015) 17–23" }, { "path": "references.16.doi", "from": null, "to": "10.1016/j.physb.2011.10.032" }, { "path": "references.16.key", "from": null, "to": "ref17" }, { "path": "references.16.unstructured", "from": null, "to": "V. Mathew, S. Jacob, C. K. Mahadevan and K. E. Abraham, Phys. B, 2012, 407, 222–226" }, { "path": "references.17.doi", "from": null, "to": "10.1016/j.optmat.2007.01.014" }, { "path": "references.17.key", "from": null, "to": "ref18" }, { "path": "references.17.unstructured", "from": null, "to": "P. Srinivasan, T. Kanagasekaran, N. Vijayan, G. Bhagavannarayana, R. Gopalakrishnan and P. Ramasamy, Opt. Mater., 30 (2007) 553–564" }, { "path": "references.18.doi", "from": null, "to": "10.1007/s10973-015-4457-8" }, { "path": "references.18.key", "from": null, "to": "ref19" }, { "path": "references.18.unstructured", "from": null, "to": "K. Syed, S. Babu, G. Peramaiyan, M. Nizam Mohideen and R. Mohan, J. Therm. Anal. Calorim., 120 (2015) 1337–1345" }, { "path": "references.19.key", "from": null, "to": "ref20" }, { "path": "references.19.unstructured", "from": null, "to": "Broadband Dielectric Spectroscopy, ed. F. Kremer and A. Schoenhals, Springer, Berlin, 2003" }, { "path": "references.2.doi", "from": null, "to": "10.1002/(sici)1521-4095(199910)11:15<1243::aid-adma1243>3.0.co;2-2" }, { "path": "references.2.key", "from": null, "to": "ref3" }, { "path": "references.2.unstructured", "from": null, "to": "S.A. Empedocles, R. Neuhauser, K. Shimizu and M.G. Bawendi, Adv. Mater., 11 (1999) 1243–1256" }, { "path": "references.20.doi", "from": null, "to": "10.1016/j.ijleo.2013.09.023" }, { "path": "references.20.key", "from": null, "to": "ref21" }, { "path": "references.20.unstructured", "from": null, "to": "S. Nazarath Begum, U. Sankar, T. ChithambraThanu and P. Selvarajan, Optik, 125 (2014) 1493–1497" }, { "path": "references.21.doi", "from": null, "to": "10.1016/s0022-0248(01)02094-2" }, { "path": "references.21.key", "from": null, "to": "ref22" }, { "path": "references.21.unstructured", "from": null, "to": "M. Narayana Bhat, S.M. Dharmaprakash, J. Cryst. Growth 236 (2002) 376–380" }, { "path": "references.3.doi", "from": null, "to": "10.1016/j.electacta.2013.11.176" }, { "path": "references.3.key", "from": null, "to": "ref4" }, { "path": "references.3.unstructured", "from": null, "to": "M. Sabet, M. Salavati-Niasari and O. Amiri, Electrochim. Acta, 117 (2014) 504–520" }, { "path": "references.4.doi", "from": null, "to": "10.1039/c4ra10316e" }, { "path": "references.4.key", "from": null, "to": "ref5" }, { "path": "references.4.unstructured", "from": null, "to": "O. Amiri, M. Salavati-Niasari, A. Rafiei and M. Farangi, RSC Adv., 4 (2014), 62356–62361" }, { "path": "references.5.doi", "from": null, "to": "10.1016/j.mssp.2014.06.020" }, { "path": "references.5.key", "from": null, "to": "ref6" }, { "path": "references.5.unstructured", "from": null, "to": "O. Amiri, M. Salavati-Niasari, S. M. Hosseinpour-Mashkani, A. Rafiei and S. Bagheri, Mater. Sci. Semiconduct. Process., 27 (2014), 261–266" }, { "path": "references.6.doi", "from": null, "to": "10.1038/nature01353" }, { "path": "references.6.key", "from": null, "to": "ref7" }, { "path": "references.6.unstructured", "from": null, "to": "X. Duan, Y. Huang, R. Agarwal and C.M. Lieber, Nature, 421 (2003) 241–245" }, { "path": "references.7.doi", "from": null, "to": "10.1063/1.365261" }, { "path": "references.7.key", "from": null, "to": "ref8" }, { "path": "references.7.unstructured", "from": null, "to": "M.V. Artemyev, V. Sperling and U. Woggon, J. Appl. Phys., 81 (1997) 6975–6977" }, { "path": "references.8.doi", "from": null, "to": "10.1021/cr00033a003" }, { "path": "references.8.key", "from": null, "to": "ref9" }, { "path": "references.8.unstructured", "from": null, "to": "A. Hagfeldt and M. Gratzel, Chem. Rev., 95 (1995) 49–68" }, { "path": "references.9.doi", "from": null, "to": "10.1038/370354a0" }, { "path": "references.9.key", "from": null, "to": "ref10" }, { "path": "references.9.unstructured", "from": null, "to": "V.L. Colvin, M.C. Schlamp and A.P. Alivisatos, Nature, 370 (1994) 354–357" }, { "path": "referent", "from": null, "to": "Creation" }, { "path": "structural_type", "from": null, "to": "Digital" }, { "path": "titles.0.lang", "from": null, "to": "en" }, { "path": "titles.0.type", "from": null, "to": "PrincipalTitle" }, { "path": "titles.0.value", "from": null, "to": "SPECTROSCOPIC MARK AND QUANTUM CHEMICAL INVESTIGATION FOR PHOTONIC/BIOLOGICAL APPLICATIONS" }, { "path": "type", "from": null, "to": "JournalArticle" } ], "record_after": { "format": "smartscholars-doi-metadata/1.0", "doi": "10.46243/jst.2023.v8.i10.pp40-57", "referent": "Creation", "type": "JournalArticle", "structural_type": "Digital", "modes": [ "Visual" ], "characters": [ "Language" ], "titles": [ { "value": "SPECTROSCOPIC MARK AND QUANTUM CHEMICAL INVESTIGATION FOR PHOTONIC/BIOLOGICAL APPLICATIONS", "type": "PrincipalTitle", "lang": "en" } ], "identifiers": [ { "type": "DOI", "value": "10.46243/jst.2023.v8.i10.pp40-57" } ], "agents": [ { "role": "author", "name": { "given": "", "family": "Mr S S Saravanakumar" }, "sequence": "first" }, { "role": "author", "name": { "given": "", "family": "Dr. M S Sameema" }, "sequence": "additional" }, { "role": "author", "name": { "given": "", "family": "Dr. P. Sivakumar" }, "sequence": "additional" }, { "role": "author", "name": { "given": "", "family": "Dr. N. Sasirekha" }, "sequence": "additional" }, { "role": "publisher", "name": { "org": "Longman Publishers" } } ], "dates": { "published": "2023", "date_type": "PublicationDate", "online": "2023" }, "language": "en", "container": { "type": "Journal", "titles": [ { "value": "Journal of Science & Technology", "type": "PrincipalTitle" } ], "identifiers": [ { "type": "ISSN", "value": "2456-5660", "medium": "electronic" } ], "volume": "08", "issue": "10", "pages": { "first": "40", "last": "57" } }, "links": [ { "url": "https://www.jst.org.in/index.php/pub/article/view/807", "return_type": "text/html", "primary": true }, { "url": "https://www.jst.org.in/index.php/pub/article/download/807/739", "purpose": "text-mining", "return_type": "application/pdf" }, { "url": "https://www.jst.org.in/index.php/pub/article/download/807/1631", "purpose": "text-mining", "return_type": "application/xml" }, { "url": "https://jst.org.in/index.php/pub/article/view/807/739", "purpose": "similarity-checking" } ], "abstract": { "value": "LGHCl - Semi-organic single crystals of L-Glutamic acid hydrochloride, optical material have been grown by the solvent evaporation route. Powder X-ray diffraction and FT-IR analysis confirmed the formation of LGHCl crystals. The optical second harmonic generation (SHG) conversion efficiency of LGHCl was determined by the Kurtz-Perry powder technique, and it is found to be 1.62 times that of potassium dihydrogen phosphate. Through the SHG dependency of average particle sizes, the relative SHG efficiency of the crystal and the phase matching characteristic of the crystal were explored. The dielectric behaviour of LGHCl single crystal as a function of temperature was examined (300–350 K). The crystal’s photoconductive properties were investigated in order to determine its photocurrent and dark current responses. The Vickers microharness analysis at room temperature was used to evaluate the mechanical hardness of the generated LGHCl single crystal. Natural bond orbital (NBO) analysis was used to investigate the molecule’s stability as a result of hyperconjugation and charge delocalization interaction. Furthermore, the total and partial density of states in the title compound was also determined. The obtained results indicate that the molecule is thermodynamically and optically stable, with a hyperpolarizability that is comparable to other molecules in its class.", "lang": "en" }, "license": { "url": "https://creativecommons.org/licenses/by/4.0/", "start": "2023-01-01", "applies_to": "vor" }, "references": [ { "key": "ref1", "unstructured": "Acharya, K. P.: Photo current Spectroscopy of CdS/ Plastic, CdS/Glass, and ZnTe /Ga As Hetero-pairs Formed with Pulsed Laser Deposition. Ph.D. Thesis, Bowling Green State University, 2009" }, { "key": "ref2", "doi": "10.1007/s12043-008-0152-7", "unstructured": "Bhattacharya, R.; Saha,S.: Growth of CdS Nanoparticles by Chemical Method and its Characterization. Pramana-Journal of Physics 2008, 71, 187-192" }, { "key": "ref3", "doi": "10.1002/(sici)1521-4095(199910)11:15<1243::aid-adma1243>3.0.co;2-2", "unstructured": "S.A. Empedocles, R. Neuhauser, K. Shimizu and M.G. Bawendi, Adv. Mater., 11 (1999) 1243–1256" }, { "key": "ref4", "doi": "10.1016/j.electacta.2013.11.176", "unstructured": "M. Sabet, M. Salavati-Niasari and O. Amiri, Electrochim. Acta, 117 (2014) 504–520" }, { "key": "ref5", "doi": "10.1039/c4ra10316e", "unstructured": "O. Amiri, M. Salavati-Niasari, A. Rafiei and M. Farangi, RSC Adv., 4 (2014), 62356–62361" }, { "key": "ref6", "doi": "10.1016/j.mssp.2014.06.020", "unstructured": "O. Amiri, M. Salavati-Niasari, S. M. Hosseinpour-Mashkani, A. Rafiei and S. Bagheri, Mater. Sci. Semiconduct. Process., 27 (2014), 261–266" }, { "key": "ref7", "doi": "10.1038/nature01353", "unstructured": "X. Duan, Y. Huang, R. Agarwal and C.M. Lieber, Nature, 421 (2003) 241–245" }, { "key": "ref8", "doi": "10.1063/1.365261", "unstructured": "M.V. Artemyev, V. Sperling and U. Woggon, J. Appl. Phys., 81 (1997) 6975–6977" }, { "key": "ref9", "doi": "10.1021/cr00033a003", "unstructured": "A. Hagfeldt and M. Gratzel, Chem. Rev., 95 (1995) 49–68" }, { "key": "ref10", "doi": "10.1038/370354a0", "unstructured": "V.L. Colvin, M.C. Schlamp and A.P. Alivisatos, Nature, 370 (1994) 354–357" }, { "key": "ref11", "doi": "10.1021/ja970754m", "unstructured": "X.G. Peng, M.C. Schlamp, A.V. Kadavanich and A.P. Alivisatos, J. Am. Chem. Soc., 119 (1997) 7019–7029" }, { "key": "ref12", "doi": "10.1016/j.matchemphys.2004.11.015", "unstructured": "X. Liu, Mater. Chem. Phys., 91 (2005) 212–216" }, { "key": "ref13", "unstructured": "D. Ghanbari, M. Salavati-Niasari, S. Karimzadeh and S. Gholamrezaei, J. NanoStruct., 4 (2014) 227–232" }, { "key": "ref14", "unstructured": "G. Nabiyouni, S. Sharifi, D. Ghanbari and M. Salavati-Niasari, J. NanoStruct., 4 (2014) 317–323" }, { "key": "ref15", "unstructured": "M. Panahi-Kalamuei, M. Mousavi-Kamazani and M. Salavati-Niasari, J. NanoStruct., 4 (2014) 459–465" }, { "key": "ref16", "unstructured": "F. Beshkar and M. Salavati-Niasari, J. NanoStruct., 5 (2015) 17–23" }, { "key": "ref17", "doi": "10.1016/j.physb.2011.10.032", "unstructured": "V. Mathew, S. Jacob, C. K. Mahadevan and K. E. Abraham, Phys. B, 2012, 407, 222–226" }, { "key": "ref18", "doi": "10.1016/j.optmat.2007.01.014", "unstructured": "P. Srinivasan, T. Kanagasekaran, N. Vijayan, G. Bhagavannarayana, R. Gopalakrishnan and P. Ramasamy, Opt. Mater., 30 (2007) 553–564" }, { "key": "ref19", "doi": "10.1007/s10973-015-4457-8", "unstructured": "K. Syed, S. Babu, G. Peramaiyan, M. Nizam Mohideen and R. Mohan, J. Therm. Anal. Calorim., 120 (2015) 1337–1345" }, { "key": "ref20", "unstructured": "Broadband Dielectric Spectroscopy, ed. F. Kremer and A. Schoenhals, Springer, Berlin, 2003" }, { "key": "ref21", "doi": "10.1016/j.ijleo.2013.09.023", "unstructured": "S. Nazarath Begum, U. Sankar, T. ChithambraThanu and P. Selvarajan, Optik, 125 (2014) 1493–1497" }, { "key": "ref22", "doi": "10.1016/s0022-0248(01)02094-2", "unstructured": "M. Narayana Bhat, S.M. Dharmaprakash, J. Cryst. Growth 236 (2002) 376–380" } ], "record": { "registrant": "Longman Publishers", "registered": "2026-08-27", "updated": "2026-09-26", "issue_number": 1, "source": "crossref-api", "source_agency": "Crossref (member 25296)" } }, "url_after": "https://www.jst.org.in/index.php/pub/article/view/807", "sha256_before": null, "sha256_after": "fb9a734c32c667859c0486d6c61596338308948ada5fad4d2a1f0263795ffdcf" }, { "seq": 2, "kind": "update", "at": "2026-09-29 23:59:51", "by": "Administrator (admin)", "by_kind": "user", "note": "record re-read from api.crossref.org", "changes": [ { "path": "container.titles.0.value", "from": "Journal of Science & Technology", "to": "Journal of Science & Technology" } ], "record_after": { "format": "smartscholars-doi-metadata/1.0", "doi": "10.46243/jst.2023.v8.i10.pp40-57", "referent": "Creation", "type": "JournalArticle", "structural_type": "Digital", "modes": [ "Visual" ], "characters": [ "Language" ], "titles": [ { "value": "SPECTROSCOPIC MARK AND QUANTUM CHEMICAL INVESTIGATION FOR PHOTONIC/BIOLOGICAL APPLICATIONS", "type": "PrincipalTitle", "lang": "en" } ], "identifiers": [ { "type": "DOI", "value": "10.46243/jst.2023.v8.i10.pp40-57" } ], "agents": [ { "role": "author", "name": { "given": "", "family": "Mr S S Saravanakumar" }, "sequence": "first" }, { "role": "author", "name": { "given": "", "family": "Dr. M S Sameema" }, "sequence": "additional" }, { "role": "author", "name": { "given": "", "family": "Dr. P. Sivakumar" }, "sequence": "additional" }, { "role": "author", "name": { "given": "", "family": "Dr. N. Sasirekha" }, "sequence": "additional" }, { "role": "publisher", "name": { "org": "Longman Publishers" } } ], "dates": { "published": "2023", "date_type": "PublicationDate", "online": "2023" }, "language": "en", "container": { "type": "Journal", "titles": [ { "value": "Journal of Science & Technology", "type": "PrincipalTitle" } ], "identifiers": [ { "type": "ISSN", "value": "2456-5660", "medium": "electronic" } ], "volume": "08", "issue": "10", "pages": { "first": "40", "last": "57" } }, "links": [ { "url": "https://www.jst.org.in/index.php/pub/article/view/807", "return_type": "text/html", "primary": true }, { "url": "https://www.jst.org.in/index.php/pub/article/download/807/739", "purpose": "text-mining", "return_type": "application/pdf" }, { "url": "https://www.jst.org.in/index.php/pub/article/download/807/1631", "purpose": "text-mining", "return_type": "application/xml" }, { "url": "https://jst.org.in/index.php/pub/article/view/807/739", "purpose": "similarity-checking" } ], "abstract": { "value": "LGHCl - Semi-organic single crystals of L-Glutamic acid hydrochloride, optical material have been grown by the solvent evaporation route. Powder X-ray diffraction and FT-IR analysis confirmed the formation of LGHCl crystals. The optical second harmonic generation (SHG) conversion efficiency of LGHCl was determined by the Kurtz-Perry powder technique, and it is found to be 1.62 times that of potassium dihydrogen phosphate. Through the SHG dependency of average particle sizes, the relative SHG efficiency of the crystal and the phase matching characteristic of the crystal were explored. The dielectric behaviour of LGHCl single crystal as a function of temperature was examined (300–350 K). The crystal’s photoconductive properties were investigated in order to determine its photocurrent and dark current responses. The Vickers microharness analysis at room temperature was used to evaluate the mechanical hardness of the generated LGHCl single crystal. Natural bond orbital (NBO) analysis was used to investigate the molecule’s stability as a result of hyperconjugation and charge delocalization interaction. Furthermore, the total and partial density of states in the title compound was also determined. The obtained results indicate that the molecule is thermodynamically and optically stable, with a hyperpolarizability that is comparable to other molecules in its class.", "lang": "en" }, "license": { "url": "https://creativecommons.org/licenses/by/4.0/", "start": "2023-01-01", "applies_to": "vor" }, "references": [ { "key": "ref1", "unstructured": "Acharya, K. P.: Photo current Spectroscopy of CdS/ Plastic, CdS/Glass, and ZnTe /Ga As Hetero-pairs Formed with Pulsed Laser Deposition. Ph.D. Thesis, Bowling Green State University, 2009" }, { "key": "ref2", "doi": "10.1007/s12043-008-0152-7", "unstructured": "Bhattacharya, R.; Saha,S.: Growth of CdS Nanoparticles by Chemical Method and its Characterization. Pramana-Journal of Physics 2008, 71, 187-192" }, { "key": "ref3", "doi": "10.1002/(sici)1521-4095(199910)11:15<1243::aid-adma1243>3.0.co;2-2", "unstructured": "S.A. Empedocles, R. Neuhauser, K. Shimizu and M.G. Bawendi, Adv. Mater., 11 (1999) 1243–1256" }, { "key": "ref4", "doi": "10.1016/j.electacta.2013.11.176", "unstructured": "M. Sabet, M. Salavati-Niasari and O. Amiri, Electrochim. Acta, 117 (2014) 504–520" }, { "key": "ref5", "doi": "10.1039/c4ra10316e", "unstructured": "O. Amiri, M. Salavati-Niasari, A. Rafiei and M. Farangi, RSC Adv., 4 (2014), 62356–62361" }, { "key": "ref6", "doi": "10.1016/j.mssp.2014.06.020", "unstructured": "O. Amiri, M. Salavati-Niasari, S. M. Hosseinpour-Mashkani, A. Rafiei and S. Bagheri, Mater. Sci. Semiconduct. Process., 27 (2014), 261–266" }, { "key": "ref7", "doi": "10.1038/nature01353", "unstructured": "X. Duan, Y. Huang, R. Agarwal and C.M. Lieber, Nature, 421 (2003) 241–245" }, { "key": "ref8", "doi": "10.1063/1.365261", "unstructured": "M.V. Artemyev, V. Sperling and U. Woggon, J. Appl. Phys., 81 (1997) 6975–6977" }, { "key": "ref9", "doi": "10.1021/cr00033a003", "unstructured": "A. Hagfeldt and M. Gratzel, Chem. Rev., 95 (1995) 49–68" }, { "key": "ref10", "doi": "10.1038/370354a0", "unstructured": "V.L. Colvin, M.C. Schlamp and A.P. Alivisatos, Nature, 370 (1994) 354–357" }, { "key": "ref11", "doi": "10.1021/ja970754m", "unstructured": "X.G. Peng, M.C. Schlamp, A.V. Kadavanich and A.P. Alivisatos, J. Am. Chem. Soc., 119 (1997) 7019–7029" }, { "key": "ref12", "doi": "10.1016/j.matchemphys.2004.11.015", "unstructured": "X. Liu, Mater. Chem. Phys., 91 (2005) 212–216" }, { "key": "ref13", "unstructured": "D. Ghanbari, M. Salavati-Niasari, S. Karimzadeh and S. Gholamrezaei, J. NanoStruct., 4 (2014) 227–232" }, { "key": "ref14", "unstructured": "G. Nabiyouni, S. Sharifi, D. Ghanbari and M. Salavati-Niasari, J. NanoStruct., 4 (2014) 317–323" }, { "key": "ref15", "unstructured": "M. Panahi-Kalamuei, M. Mousavi-Kamazani and M. Salavati-Niasari, J. NanoStruct., 4 (2014) 459–465" }, { "key": "ref16", "unstructured": "F. Beshkar and M. Salavati-Niasari, J. NanoStruct., 5 (2015) 17–23" }, { "key": "ref17", "doi": "10.1016/j.physb.2011.10.032", "unstructured": "V. Mathew, S. Jacob, C. K. Mahadevan and K. E. Abraham, Phys. B, 2012, 407, 222–226" }, { "key": "ref18", "doi": "10.1016/j.optmat.2007.01.014", "unstructured": "P. Srinivasan, T. Kanagasekaran, N. Vijayan, G. Bhagavannarayana, R. Gopalakrishnan and P. Ramasamy, Opt. Mater., 30 (2007) 553–564" }, { "key": "ref19", "doi": "10.1007/s10973-015-4457-8", "unstructured": "K. Syed, S. Babu, G. Peramaiyan, M. Nizam Mohideen and R. Mohan, J. Therm. Anal. Calorim., 120 (2015) 1337–1345" }, { "key": "ref20", "unstructured": "Broadband Dielectric Spectroscopy, ed. F. Kremer and A. Schoenhals, Springer, Berlin, 2003" }, { "key": "ref21", "doi": "10.1016/j.ijleo.2013.09.023", "unstructured": "S. Nazarath Begum, U. Sankar, T. ChithambraThanu and P. Selvarajan, Optik, 125 (2014) 1493–1497" }, { "key": "ref22", "doi": "10.1016/s0022-0248(01)02094-2", "unstructured": "M. Narayana Bhat, S.M. Dharmaprakash, J. Cryst. Growth 236 (2002) 376–380" } ], "record": { "registrant": "Longman Publishers", "registered": "2026-08-27", "updated": "2026-09-26", "issue_number": 1, "source": "crossref-api", "source_agency": "Crossref (member 25296)" } }, "url_after": "https://www.jst.org.in/index.php/pub/article/view/807", "sha256_before": "fb9a734c32c667859c0486d6c61596338308948ada5fad4d2a1f0263795ffdcf", "sha256_after": "dd80b0d87f0dfe1ea594bee9eb5552802612eeef9030d5298d15143a3f192205" } ] }